Hydrocarbon alkenes nomenclature

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Naming of hydrocarbons alkenes or olefins
Naming of alkenes

The structural formula of alkenes

    Organic compounds contain at least one pair of adjacent carbon atoms linked by multiple bonds, then that compound is said to be unsaturated.

Hydrocarbon ethylene and acetylene

    Ethylene contains a double bond. There are only four univalent hydrogen atoms present in ethylene, therefore ethylene said to be an unsaturated compound.
H₂C = CH₂
    Acetylene contains a triple bond and there are only two univalent hydrogen atoms.

Naming organic compounds alkenes

    Alkenes are the hydrocarbons that contain one double bond. They have the general formula CnH2n, as they contain two hydrogen atoms less than the alkanes, alkenes are called unsaturated hydrocarbons.
    The double bond is called 'olefinic bond or 'ethylenic bond'. The name olefin arose from the fact that ethylene was called 'olefiant gas'( oil-forming gas) since it forms oily liquids when treated with chlorine or bromine.
    The original name given to this homologous series was olefine, but it was later decided to reserve the suffix - ine for basic substances only.

Common naming of alkenes

    In the common naming system of an olefin is named according to the following rules,
    The total number of carbon atom in the olefin is counted and the name of the corresponding alkane is determined.
the corresponding alkane is ethane
    By changing the name of the corresponding alkane, the suffix -ane of the latter into - ylene.
For ethane changing the suffix -ane of the latter into - ylene.
    The position of the double bond is indicated by number 1, 2, 3, 4...., or Greek Letters α, β, ⋎, ઠ, ...., the end carbon atom nearest to the double bond is denoted by 1, next 2,and so on or α, next β, and so on.
    These letters are then known as locants. The locants of the double bond carbon atom are then placed before the name of the olefin as obtain from rules 1 and 2.
    A hyphen is written in between the locants and the name. The locants are used only to name alkenes containing more than three carbon atoms. alkenes of low molecular weights only have common names.
    Write down the common names of the following compounds: (i) CH3CH2CH2CH=CH2 (ii) CH3CH=CHCH2CH3.
(i) CH₃ - CH₂ - CH₂ - CH=CH2
Parent alkane is pentane

Thus the name of the compound is,
1 - pentylene or α - pentylene

(ii) CH3 - CH = CH - CH2 - CH3
Parent alkane is pentane

Thus the name of the compound is
2 -pentylene or β - pentylene

Substituted or derived naming of alkenes

    Another method of nomenclature is to consider ethylene as the parent substance and higher member is derivatives of ethylene.
    If the compound is mono-substituted then no difficulty arises in naming. The compound is a disubstituted derivative of ethylene isomerism is possible. Since the alkyl groups are of attached the same or different carbon atoms.
    When the groups are attached to the same carbon atom of the olefins named as the asymmetrical compound.
    When the groups are attached to the different carbon atom of the olefins named as the symmetrical compound.
CH3 ㄧCH = CH2
CH3ㄧCH2ㄧCH = CH2
CH3 ㄧ(H3C)C = CH2
as - dimethyl ethylene
sym - dimethyl ethylene

IUPAC naming of alkenes

    According to the I.U.P.A.C. system of nomenclature, the class suffix of the olefins is - ene, and so the series becomes the alkene series.
  1. The longest carbon chain containing the double bond is chosen as the parent alkene.
    The parent part is here base chain, it consists of 8 carbons. The basename, therefore, is to be derived from octane.
  2. The position of the double bond and side chains are indicated by numbers, the lowest number possible being given to the double bond, and this is placed before the suffix.
  3. Study IUPAC naming alkenes in organic chemistry
    IUPAC naming alkenes
  4. The name of which is obtained by changing the suffix - ane of the corresponding alkanes into - alkenes.
    To give the lowest number of possible double-bonded carbon is numbered 3.
  5. There are four branches, One methyl branch on carbon atom number 3, three methyl branches on 5th and 7th carbon atoms.
    These are to be indicated as prefixes to the base name. Their names with their locants are 3, 5, 7, 7 - tetramethyl.
Hence the full name is,
3, 5, 7, 7 - tetramethyl - 3 - octene

IUPAC naming of the organic compunds

    What are the names of the following compounds in the IUPAC system ? (i) CH3 - CH2 - CH = CH2 (ii) C(CH3)2 = CH2 (iii) CH3 - CH = C(CH3) - CH2 - CH3 (iv) CH2 = C(C2H5) - CH(CH3)2
(i) CH₃ - CH₂ - CH = CH₂

(ii) (CH₃)₂C = CH₂

(iii) CH₃ - CH = C(CH₃) - CH₂ - CH₃

(iv) CH₂ = C(C₂H₅) - CH(CH₃)₂
    Write out the (ignoring stereochemistry) of the isomeric pentanes, and name them by the IUPAC system. Give the structures of the products formed from each on ozonolysis.
    The molecular formula of the pentene is C₅H₁₂.
    Now take each one in turn and introduce one double bond, starting at the least substituted end and shifting the double bond inwards.




    The product obtained from the ozonide depends on the nature of the reagents used. Here we small use of zinc and acid to give aldehyde and/or ketones.










Hydrocarbon alkenes nomenclature, the structural formula of alkenes study online common and IUPAC meaning in organic chemistry with examples

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