Energy Levels of Hydrogen Atom
Bohr’s Model of hydrogen atom adopted by Neils Bohr in 1913 for the explanation of Rutherford’s theory and atomic spectrum of hydrogen energy levels. According to classical mechanics, when a charged electron subjected to the acceleration it emits radiation and energy released to hit the nucleus of an atom. Therefore, according to Rutherford atomic theory, the electron loses energy continuously and the observed spectra should be continuous spectra. But the actual electromagnetic spectrum consists of well-defined lines of definite frequencies and wavelengths. To resolve these anomalous Niels Bohr uses a new model for the hydrogen atom or one electronic system of the chemical elements.
Bohr Model of Hydrogen Atom Postulates
- An atom possesses several stable circular orbitals in which an electron can stay. Thus an electron stays in a particular orbit where no emission or absorption of energy occurs. These orbits are called energy levels of an atom.
The energy levels designated by numbers 1, 2, 3, …….. or capital letters, K, L, M, …….. starting from the nucleus of the atom. Thus the energy associated with a certain energy level increases with the increase of its distance from the nucleus. If E1, E2, E3 …… denotes the number of energy levels of 1 (K-shell), 2 (L-shell), 3 (M-shell) ……. then the order of energy levels are, E1ㄑE2ㄑE3ㄑ……
- When an electron can jump from one orbit to another higher energy on the absorption of unit energy but one orbit to another lower energy with the emission of unit energy.
- The angular momentum of an electron moving in an orbit is an integral multiple of h/2π. This integral multiple is known as the principal quantum energy levels of hydrogen.
∴ mvr = nh/2π
where m = mass of an electron,
v = tangential velocity of an electron,
r = radius of an atom and
Nucleus Electrons Attraction in Hydrogen Atom
Let the nucleus has a mass m′ and the electron has mass m, the radius of the circular orbit = r, and the linear velocity of the electron = v.
On the revolving electron, two types of forces acting, centrifugal force and the electric force of attraction. Hence the centrifugal force = mv2/r and electric force of attraction between two opposite charges = e2/r2 (given from Coulomb’s law for the polar bond).
Centrifugal force and electric force acted in the opposite direction. Thus the electron may keep on revolving in its orbit if these two forces act in the opposite direction must balancing by each other. Therefore, mv2/r = e2/r.
Radius of Hydrogen Energy Levels
The remarkable study from Niels Bohr atomic theory, the angular momentum of the electron is an integral multiple of h/2π.
mvr = nh/2π
where mvr = angular momentum,
n = having the values 1,2,3, ……∞.
or, v = nh/2πmr
Putting the value of v on the force equation
r = n2h2/4π2me2
First Orbit of Hydrogen Atom Radius
From the above equation, we can easily find out the radius of the permitted energy levels by use hydrogen in terms of the quantum number. When n = 1, the radius of the first stationary orbit of hydrogen (r1) = 0.529 × 10-8 cm = 0.529 Å. Therefore, the ratio of first Bohr orbit and nth orbit of the hydrogen atom, rn = n2 × r1.
Question: Calculate the radius of the second orbit of hydrogen if the radius of the first orbit of hydrogen = 0.529 Å.
Answer: The radius of the second orbit of the hydrogen atom (r2) = n2 × r1 = 2.12 Å
Velocity of an Electron in Hydrogen Atom
From the principle of quantization to the revolving electron in the hydrogen atom, mvr = nh/2π. When we putting the values of r in mvr = nh/2π and solving, we have velocity (v) = 2πe2/nh. Therefore, the velocity of the second orbit will be one half of the first orbit and one-third of the first orbit and so on.
Problem: Calculate the velocity of the hydrogen electron in the first and third energy levels of an atom. How to calculate the number of rotation of an electron per second in the third energy level?
Solution: The velocity of an electron nth level of the hydrogen atom (vn) = 2πe2/nh, where n = 1, 2, 3, …….. Thus the velocity of an electron in the first energy level (v1) = 2πe2/12 × h = 2πe2/h = 2.188 × 108 cm sec-1.
The velocity of the third energy level (v3) = v1/3 = (2.188 × 108 cm sec-1)/3 = 7.30 × 107 cm sec-1. The radius of the third energy level = 32 × 0.529 × 10-8 cm. Hence, the circumference of the third energy level = 2πr = 2 × 3.14 × 0.529 × 10-8 cm.
Thus the rotation of an electron per second in the third energy level of the hydrogen = (7.30 × 107)/(2 × 3.14 × 9 × 0.529 × 10-8 ) = 2.44 × 1014 sec-1.
Energy of an Electron in Hydrogen Atom
The energy of an electron moving in one particular energy level can be calculated by the total energy or the sum of the kinetic energy and the potential energy of an electron in physical and chemical science. Here kinetic energy = ½ mv2 and potential energy for moving electron = e2/r. Thus the total energy for the nth level of the hydrogen atom,
En = (1/2mv2) + (- e2/r) = – 1/2mv2
∴ En = – e2/2r, where mv2 = e2/r
Putting the value of r in the above equation
Etotal = – 2π2me4/n2h2
Therefore, En = E1/n2, where E1 = energy of the first orbit of the hydrogen atom. As n increases the energy becomes less negative and hence the system becomes less stable. Because with increasing n, r also increases and orbit makes less stable. If the energies associated with 1st, 2nd, 3rd,…., nth orbits are E1, E2, E3 … En, hence, E1ㄑE2ㄑE3ㄑ……..ㄑEn.
Electron Energy Calculation in Bohr Orbit
The energy of the moving electron in the first energy levels obtained by putting n=1 in the Bohrs energy expression of the hydrogen. Efirst energy level = – 21.79 × 10-12 erg = – 13.6 eV = – 21.79 × 10-19 Joule = – 313.6 Kcal.
Question: H, H+, He+ and Li+2 – for which of the species Bohr’s model of the hydrogen atom is not applicable?
Answer: From the above species H, He+, Li+2 contain one electron but H+-ion has no electron. But the Bohr’s model of hydrogen atom applicable for one electronic system. Thus for H+-ion, this model is not applicable.