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Emulsion

What is emulsion?

Emulsion in chemistry is formed when a liquid is dispersed in another liquid that is not miscible to each other. Milk is a bright example of emulsion where facts are dispersed in water by emulsifying agents like protein casein. It is a two-phase system of matter like colloids.

Types of emulsion in chemistry like oil in water and water in oil

Types of Emulsions

Emulsions are classified into two types like oil in water type and water in oil type. Here, oil is synonymous with any liquid which is immiscible with water. In oil in water type emulsion, oil is dispersed in medium water. In the water in oil type emulsion, water is dispersed in the medium oil.

Identification

The two types of emulsions may be identified by pouring water on them. In oil in water type emulsion, water is soluble in the solution. In the water in oil type emulsion, oil is soluble in the solution. Sometimes, an electrolyte is added to the emulsion and the conductance is found to increase, then it is identified as oil in water type.

Emulsifying Agent

Generally, an emulsion is stabilized by introducing third substances like emulsifying agents. These agents are three types like soap and detergents, lyophilic sols, and insoluble powder.

Soap and detergents

These are the sodium or potassium salts of long-chain fatty acids and sulphonates. They are surfactants that reduce the surface tension between a liquid and another medium and are used as emulsification agents.

Lyophilic sols

Lyophilic sols are very stable emulsifying agents that have strong interaction forces between the dispersed phase and dispersion medium. Rubber, starch, proteins, albumin, and gelatine are examples of lyophilic emulsifying agents.

Insoluble powder

These are basic sulfates of iron, copper, or nickel, lead sulfate (PbSO4), iron(III) oxide or ferric oxide (Fe2O3), etc. The emulsifying agents tend to decreases the surface tension at the oil-water interface to facilitate the formation of globules or droplets.  Milk is an emulsion of fat in water (oil in water type) and stabilizes by emulsifying agent casein protein.

Properties of emulsion

The behavior of emulsion in the absence of emulsifying agent resembles that of lyophobic sols. They show the Tyndall effect, Brownian motion, low viscosity, electrophoresis, etc. The globules move towards the electrode (anode) at the mobility of 1 × 10-4 cm2 sec-1 volt-1.

The behavior of emulsion in the presence of emulsifying agent resembles that of lyophilic sols. They are highly viscous, insensitive to electrolytes. Chemical destruction of emulsifying agents destabilizes the emulsions and it is called de-emulsification. If soap or detergents are used as emulsifying agents, they can be destroyed by hydrolysis. The physical method like centrifuge or getting used to destroy it.

Mechanism of Emulsification

Emulsifying agent decreases the surface tension at the oil-water interface. It is found that the nature of the substances plays a great role in the formation of different types of emulsions. For example, if sodium-oleate is used, it becomes oil in water type. When calcium-oleate is used, the emulsion becomes water in oil type. The fact can be explained in the following way. Sodium-oleate is preferably dissolved in water and the surface tension of water decreases that facilitating the formation of oil in the water-type emulsion.