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Hydrogen Bonding

What is hydrogen bonding?

Hydrogen bonding or intermolecular and intramolecular hydrogen bond is the weak type of chemical bond due to very unstable attractive forces responsible for the formation of H-bond in learning chemistry or chemical science. A common example of intramolecular hydrogen bonding is seen in the dimer of formic acid, acetic acid, o-hydroxybenzaldehyde, o-nitrophenol, and intermolecular hydrogen bonding in water, ammonia, hydrogen fluoride, etc. Some examples of the formation of hydrogen bonds are given below the picture.

Hydrogen bonding, examples of intermolecular and intramolecular hydrogen bond in water, ice, ortho-nitrophenol

Types of hydrogen bonding

It is mainly two types, intramolecular and intermolecular Hydrogen Bonding. The electronic configuration of hydrogen is 1s1. The nucleus of hydrogen is surrounded by only one electron in 1s orbital with the maximum capacity of two electrons. Therefore, hydrogen has the capability for forming a single covalent chemical bond but if the covalently bonded another atom is a strongly electronegative chemical element, the bonds become polar.

From the definition of electric polarization, the positive hydrogen end of the dipole can weakly link or bond with another negative dipole end present in the same molecule like o-nitrophenol or another molecule like water, ice, ammonia, etc. This weak secondary link between two electronegative atoms through hydrogen atoms is defined as intramolecular or intermolecular hydrogen bonding.

Intermolecular Hydrogen Bonding

The hydrogen linking occurring between two or more similar or different molecules is called the intermolecular hydrogen bond. Water, ammonia, and hydrogen fluoride are examples of such types of molecules.

Hydrogen bonding in HF

In hydrogen fluoride (HF), the positive end of one dipole attracts the negative end of another similar dipole. These molecules are associated together to form the cluster, (HF)n.

Hydrogen bonding in water

Hydrogen bonding in water leads to the molecular association of H2O molecules. Such types of molecular association of water form the polymerize molecule like (H2O)n in which hydrogen acts as a bridge between two highly electronegative oxygen atoms. The hydrogen bond in water is important to the exitance of our world. In absence of hydrogen bonds, water would be a gas at ordinary temperature. Therefore, without liquid water, we cannot imagine animal or vegetable life.

In hydrogen sulfide, due to the small electronegativity of sulfur atoms, H2S does not form (H2S)n type cluster by hydrogen link. Therefore, water exists in liquid form but hydrogen sulfide exists as a gas molecule.

Intramolecular hydrogen bonding

The hydrogen linking occurring within the single molecules is called intramolecular hydrogen bonding. Hence intramolecular H-bond gives rise to ring formation or chelation. For an example of aromatic alcohol like o-nitrophenol defines an intramolecular hydrogen bond.

Intramolecular hydrogen bonding examples in Ortho hydroxybenzaldehyde and o-nitrophenol

Application of hydrogen bonds

The unstable link or hydrogen bond uses to explain the unexpected physical properties like density, melting point, the boiling point of the solid, liquid, gaseous inorganic, and organic molecule. For example, the crystalline solid form of phenol or carboxylic acid is supported due to the formation of the hydrogen bond.

Hydrogen bonding in acetic acid

o-nitrophenol and p-nitrophenol boiling point

Therefore, o-nitrophenol boils at 214°C, while m- and p-isomer boils at 290°C and 270°C respectively. Here o-nitrophenol has a hydrogen bond limited within the same molecule but p- and m-nitrophenol extends to the neighboring molecules. Hence the p- and meta nitrophenol gathering a large number of the molecule through the hydrogen bond.

Ortho hydroxybenzaldehyde

Ortho hydroxy benzaldehyde also restricted hydrogen-bond within the molecule. It leads to weakening acid properties of the compound. Due to H-bonding, the scope for the formation of hydrogen ions in the solution is limited which increases the pH scale of the solution.

Properties of hydrogen bond

The bond energy of the hydrogen bonding is in the range of 3 to 10 kcal mol-1 but in normal covalent bonds in the range of 50 to 100 kcal mol-1. Therefore, a normal covalent bond is a strong bond than weaker hydrogen bonds present in inorganic or organic compounds. It does not involve any sharing of the electron particles. Hence the characteristics of the hydrogen bond are quite different from the normal covalent bond.

Strength of hydrogen bond

The strength of hydrogen bonds is directly related to the electronegativity and polarity of bonds between the periodic table elements. With the increasing electronegativity or electron affinity, the strength of hydrogen bonds also increases. For example, the H-bonding strength of ammonia < water < hydrogen fluoride. The hydrogen bond is detected by the electromagnetic spectrum in absorption spectroscopy, infrared spectrum, and x-ray method.

Hydrogen bonding in ice

Ice is a crystalline solid. In the ice crystal lattice, the oxygen-atom tetrahedrally is surrounded by four hydrogen atom. Two hydrogen atoms are linked to the oxygen atom by a covalent bond. The remaining two hydrogen atoms are linked to the oxygen atom of other water molecules by a hydrogen bond. Therefore, in ice crystal dimensions every water molecule is associated with the other four water molecules by hydrogen bonding in a tetrahedral fashion with a large amount of space.

Why density of water is maximum at 277K?

When ice heat melts from o to 4°C or 277K, the hydrogen bonds are broken down and the space between water molecules decreases. Therefore, the density of water is maximum at 4°C or 277K. Above 4°C, the kinetic energy of the molecules is sufficient to disperse from each other, and the concentration steadily decreases to form water due to breaking Hydrogen-bond.

Importance of hydrogen bonding in water

In chemical and biological science, the hydrogen bond is very important for the existence of our environment or our life. Due to the absence of hydrogen bonds, the liquid water or ice would be in the gas phase at ordinary temperatures. Without liquid water or the absence of hydrogen bonding, we can not imagine the existence of an animal or vegetable life in our environment.