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Alcohol

Types of Alcohol in Chemistry

Types of alcohol uses for the manufacture of drinks or beer, vodka, and brandy is ethyl alcohol or ethanol. Many monohydric, polyhydric, aromatic, and aliphatic alcohols are used in different alcoholic content like food beverages and drug preparation.

Classification and types of alcohols uses like monohydric or polyhydric alcohol in chemistry

Alcohol is the isomers of ether or hydroxyl derivative of hydrocarbon prepared from alkene with specific heat and dilute sulfuric acid under pressure.

Properties of alcohol

The lower members of alcohol are liquids and lees volatile due to association through hydrogen bonding extending over a chain of molecules. The higher members are solid and almost orderless.

The lower alcohols are very soluble in water and solubility diminishes as molecular weight increases because the oxygen atom of the hydroxyl group forms hydrogen bonding with water molecules.

Infrared spectrum studies of hydroxyl groups in alcohol show they absorbed electromagnetic spectrum radiation with a frequency from 3650 to 3580 cm−1. It is true only if there is no hydrogen bonding. Intermolecular hydrogen bonding in alcohols produces absorption in the region from 3550 to 3230 cm−1.

Acidic nature of alcohol

Alcohol withdrawal hydrogen atom by the action of metals shows acid properties. They do not affect the pH scale of the water solution because they are weaker acids than water.

The alkoxides beings hydrolyzed by water. For this reason, ethoxide is a stronger base than the hydroxide ion.

Classification of alcohol

According to the number of functional or alcoholic groups, these organic compounds in chemistry are classified,

  1. Monohydric alcohol
  2. Dihydric alcohol
  3. Trihydric alcohol
  4. polyhydric alcohol

But other types of classification of alcohol are given according to the attached alcoholic group to the aromatic or aliphatic compounds or hydrocarbon.

Monohydric alcohol

Monohydric alcohols are organic compounds that contain one alcoholic or hydroxyl group.

Methanol, ethanol, propanol, isopropanol, butanol, isobutanol, and phenol are examples of such types of alcohol. They are commonly two types,

  • Aromatic alcohols
  • Aliphatic alcohols

Formula of monohydric alcohol

The monohydric alcohols are the simplest with the general molecular formula, CnH2n+2O or CnH2n+1OH. Monohydric alcohols are further classified according to the alcoholic group attached to the alkyl.

  • Primary alcohol: Alcoholic group is attached to the alpha carbon atom.
  • Secondary alcohol: Alcoholic group is attached to the beta carbon atom.
  • Tertiary alcohol: Alcoholic group is attached to the gamma carbon atom.

Classification of alcohol like primary, secondary and tertiary alcohols with examples

Polyhydric alcohol

Dihydric and trihydric alcohol contain two or three alcoholic or hydroxyl groups. But the alcohols contain four or more alcoholic groups called polyhydric alcohols. Such types of alcohol may include,

  • Ethylene glycol
  • Trimethylene glycol
  • Pentamethylene glycol
  • Isobutene glycol

Aromatic alcohol

Aromatic alcohols are the class of organic compounds containing an alcoholic or hydroxyl group in a side chain or directly to the hydrocarbon. It may be regarded as an aryl derivative of aliphatic alcohols.

Aromatic alcohols may be classified as primary, secondary, and tertiary alcohols. The methods of preparation of this type of alcohol are similar to the aliphatic alcohols.

Types of aromatic alcohol

Aromatic alcohols are also classified as monohydric, dihydric, trihydric, and polyhydric phenols, according to the hydroxyl group attached to the benzene ring. Common examples of this types of alcohol are,

  • Phenol
  • Catechol (o-dihydroxybenzene)
  • Resorcinol (m-dihydroxybenzene)
  • Quinol (p-dihydroxy benzene)

Aliphatic alcohols

Classification of alcohol is given according to the attached alcoholic group to the aromatic or aliphatic hydrocarbon. Hence these organic compounds are named aliphatic and aromatic alcohols. Aliphatic alcohols are compounds containing hydroxyl groups in the side chain of the alkyl group.

Types of aliphatic alcohol

  • Monohydric aliphatic alcohols: These chemicals contain one alcoholic group. Methanol, ethanol, propanol, isopropyl alcohol, butanol, and isobutanol are examples of monohydric alcoholic compounds.
  • Dihydric aliphatic alcohols: These chemicals contain two alcoholic groups. Ethylene glycol, trimethylene glycol, pentamethylene glycol, and isobutene glycol are dihydric types of alcoholic compounds.
  • Trihydric aliphatic alcohols: These chemicals contain three alcoholic groups. The only important trihydric aliphatic organic compound is glycerol or propane-1-2-2-triol. Glycerol occurs in almost all animals and vegetable oils.
  • Polyhydric aliphatic alcohols: D-sorbitol, D-mannitol, and dulcitol are polyhydric aliphatic alcohols that naturally contain more than three hydroxyl groups.

Chemical names and formula

Different types of simpler monohydric alcohols are known by their trivial names for learning chemistry. This type of naming is obtained from the chemical derivative of the alkanes or paraffin like methane, ethane, and propane attached to the hydroxyl or alcoholic group.

Examples of alcohol
Names Formula
methanol CH3OH
n-propanol CH3CH2CH2OH
iso-propanol CH3CH(OH)CH3
t-butanol (CH3)3COH

Other types of naming by considering alcohols as the derivative of methanol. For example,

  • CH3CH2CH3OH naming as ethyl methanol
  • CH3CH2CH(OH)CH3 naming as methyl ethyl methanol

Uses of Alcohol

  • They are commercially essential organic chemical compounds. They are used mainly in alcoholic wine or beverages like vodka, beer, whisky, etc.
  • They are used as a solvent for paints, varnishes, shellac, celluloid, and cement plant.
  • When ethanol mixed with small amounts of methanol forms methylated spirit. It is used for making automobile antifreeze mixture and remove ink from various kinds of surfaces.
  • Alcohol uses for manufacturing dyes and antibiotics drugs, perfumes, etc.
  • Ethanol is used as an alternate fuel for the motor vehicle or energy generation (renewable energy) process.
  • Common alcohols like Phenol, methanol, ethanol are used as an antiseptic, alcohol-based hand sanitizer, and preparation of antibiotics drugs or bakelite.

Methods of preparation of alcohols

The common methods of preparation of alcohols are given below the picture,

general method of preparation of alcohol

Hydrolysis of alkyl halides

Alcohols may be prepared by hydrolysis of an alkyl halide with silver oxide suspended in water.

It is also prepared by hydrolysis of esters with alkali. This method is important for the preparation of tertiary alcohols.

Bouveault Blanc reduction

Reduction of the aldehydes, ketones, or esters by excess sodium in ethanol or n-butanol gives alcohols. The process is called Bouveault Blanc reduction.

Heating ethers

it may be prepared by heating ethers with dilute sulfuric acid under pressure. For example, diethyl ether forms ethanol.

Hydration of alkenes

Alkenes may be hydrated to alcohols by absorption in concentrated sulfuric acid followed by hydrolysis of the alkyl sulfate with water.

Hydroboration of alkenes

Alkenes react rapidly with diborane (B2H6) in ether or THF at room temperature producing trialkyl boranes. Trialkyl boranes on oxidation with alkaline hydrogen peroxide produces primary alcohols.

Alcohols from Grignard reagent

Primary, secondary, and tertiary alcohols may be prepared from appropriate carbonyl compounds by the action of the Grignard reagent.

Yeast fermentation process

Fermentation in the environment is the earliest method for the preparation of ethanol by the chemical catalyst and uses for the manufacture of different types of drinks brands like beer, wine, whisky, and brandy.

  • The common materials used for these chemical equilibrium reactions are wheat, barley, or potato.
  • The mashed materials boil at 50 °C for one hour. The melt contains the enzyme diastase effects on starch to convert maltose and sugar by hydrolysis,
    2 (C6H10O5)n + n H2O → n C12H22O11
  • The liquid is cooled to 300 °C and fermented with yeast for 1 to 3 days. Yeast contains various enzymes, among which maltase converts maltose into glucose.
  • Zymase further converted glucose into ethanol.

The carbon dioxide gas is recovered and sold as a by-product. The fermented liquor contains 6 to 10 percent alcohol used for the manufacture of wine, beer, brandy, or other types of food beverages.