What is Molecule?

A molecule in chemistry or biology is the smallest identifiable unit formed by two or more atoms and it retains the chemical properties of formation substances. Different types of forces or chemical bonding are responsible for the formation of most types of molecules.

Examples of polar and nonpolar molecules

In many crystalline solid molecules, the atoms are the structural units and these atoms are held together by ionic, covalent, or hydrogen bonding.

Examples of Polar and Non-polar Molecules

Covalent molecules are composed of positively charged nuclei and negatively charged electrons distributed in space. According to the structural arrangement and polarity, molecules are two types

  1. Polar molecules
  2. Non-polar molecules

Polar Molecule

A polar molecule is one in which there is a separation of the centers of gravity of positive and negative charges. The molecule developed a positive and a negative pole. Normally, heteronuclear diatomic molecules are polar due to the difference in electronegativity in bonding atoms.

The polar character of a molecule is described by the term dipole moment. Examples of some common polar molecules are,

Example of molecule Molecular formula Dipole Moment (Debye)
Hydrogen fluoride HF 1.91
Water H2O 1.85
Hydrogen sulfide H2S 1.10
Hydrogen chloride HCl 1.03
Hydrogen bromide HBr 0.78
Ammonia NH3 1.46
Sulfur dioxide SO2 1.63
Carbon monoxide CO 0.12
Nitrous oxide N2O 0.17
Nitrogen trifluoride NF3 0.20

Non-polar Molecule

The non-polar molecule is one where the center of gravity of the positive charge due to nuclei coincides with the center of gravity of the negative charge due to electron.

Binary homonuclear molecules are non-polar since the bonding elements possess the same electronegativity. Examples of some common non-polar molecules are,

Examples of molecules Molecular formula Dipole Moment (Debye)
Hydrogen H2 0
Chlorine Cl2 0
Phosphorus pentachloride PCl5 0
Carbon dioxide CO2 0
Carbon disulfide CS2 0
Carbon tetrachloride CCl4 0
Boron trifluoride BF3 0
Benzene C6H6 0
Stannic chloride SnCl4 0
Beryllium chloride BeCl2 0

Structure of Molecules

The ionic and covalent bonding molecules are held together in a three-dimensional structure.

  • The ionic molecules formed a three-dimensional crystal structure.
  • Covalent molecules are formed by sharing electron pairs between atoms.
  • In the metallic crystal, a single molecule is formed by metallic bonding.

After the development of quantum mechanics, two alternative theories and hybridization are used to explain the structure of different types of covalent molecules.  These theories are valence bonds and molecular orbital theory.

Examples of Resonance

When the chemical properties of the molecules cannot be described by a single structural diagram, it forms different types of molecular structures, the true structure in chemical science means the resonance hybrid of the pure molecule. Resonance provides the different types of electronic structures of molecules.

The resonance hybrid of acetic acid and ozone gas molecules is given below the picture,

Structure and resonance hybrid of ozone gas molecule

Structure and resonance hybrid of acetic acid molecule

What is Hybridization?

In chemistry, hybridization is the mixing of pure atomic orbitals to give an equal number of hybridized orbitals. For example, the carbon atom in the methane molecule is sp3 hybridized.

Hybridization Rules

  • Only orbitals of similar energies belonging to the same atom or ion can be hybridized together.
  • The number of hybridized orbitals produced is equal to the number of orbitals undergoing hybridization.
  • Most of the orbitals are similar but they are not necessarily identical shapes.
  • From the type of hybridization, one can predict the geometry and bond angle of a molecule.

Types of Hybridization

sp, sp2, and sp3 are the most common type of hybridization for the molecules. The type of hybridization predicts the shape of the molecules. Some common examples are given below the table,

Molecule Types of hybridization Shape
BeCl2 sp linear
CO2 sp linear
BCl3 sp2 trigonal planar
SnCl2 sp2 V-shape
CH4 sp3 tetrahedral
H2O sp3 V-shape
PF5 sp3d trigonal bipyramidal
ClF3 sp3d T-shape
SF6 sp3d2 octahedral

sp hybridization

A linear combination of one s and one px orbitals in suitable proportion gives two sp hybridized orbitals. This type of hybridization is called sp hybridization. The mixing of one s and one px is given below the picture,

sp and sp2 types of hybridization of molecule in chemistry

sp2 hybridization

The mixing of one s and two p (px and py) atomic orbitals gives three sp2 hybridized orbitals. The formation of sp2 hybridized orbitals is given above the picture. In sp2 hybridization, the hybridized orbitals formed a trigonal planner structure.

sp3 hybridization

One s and three p atomic orbitals mix together to form four equivalent sp3 hybridized orbitals. This type of mixing of atomic orbitals is called sp3 hybridization. The formation of tetrahedral sp3 hybridized orbitals is given below the picture,

sp3 types of hybridization of molecule in chemistry with examples

Examples of Molecules

Structure of Carbon Dioxide Molecule

A carbon dioxide molecule is an example, formed by the components like one carbon and two oxygen atoms having linear structural formulas.

The valence shell electronic configuration of chemical element carbon in excited state 2s1 2px1 2py1 2pz1. Oxygen atoms (normal state) 2s2 2px1 2py1 2pz1.

The liner shape of O=C=O suggests that the carbon atom is the central atom with sp-hydridized. Two sp-hybrid orbitals of carbon atoms overlap with two oxygen atoms to form two sigma bonds. Another two half-filled 2p-orbitals carbon atoms bound by pi bonds with two oxygen atoms.

The experimental bond length between carbon-oxygen in carbon dioxide molecule = 1.15 Å. The resonating structure of the carbon dioxide molecule is equivalent to a resonance bond energy of 33 kcal/mole.

BCl3 Hybridization

Boron trichloride and trifluoride molecules The boron atom is the central atom in the BCl3 molecule in chemistry. The valence shell electronic configuration of the boron atom in the excited state, 2s1 2px1 2pz1.

On hybridization, these atomic orbitals form three sp2 hybrid orbitals. These hybridized orbitals overlap with three singly filled 3pz orbitals of the chlorine atom to form three B-Cl sigma bonds. Therefore, the BCl3 molecule is a trigonal planner shape.

In this molecule central atom boron with an incomplete octet. From the definition of Lewis acids bases, BCl3 molecule affinity to accept electron pair acts as a Lewis acid by forming a coordinate covalent bond with other molecules or Lewis bases.

Methane Molecule

The methane molecule is the simplest hydrocarbon of an alkane or paraffin molecule having molecular formula CH4. In methane molecules, exited carbon atoms look like 2s1 2px1 2py1 2pz1 electronic configuration.

Mixing these four atomic orbitals give four equivalent sp3-hybrid orbitals. These hybrid orbitals are directed toward the corners of the regular tetrahedron. Therefore, each sp3-hybrid orbitals overlap with the 1s-atomic orbitals of four hydrogen atom by the formation of four sigma bonds in the methane molecule.

Structure of Ammonia Molecule

In the ammonia molecule nitrogen atom is the central atom, define valence shell electronic structure, 2s2 2px1 2py1 2pz1. Therefore, four atomic orbitals of nitrogen hybridized to form four equivalent sp3-hybrid orbitals.

Three of these four orbitals in ammonia molecule overlap with 1s-orbitals of hydrogen to form three sigma-bond and the remaining hybrid orbitals contain a lone pair of electrons. The ammonia molecule looks like a distorted tetrahedral shape with a bond angle of 107.5º.

Structure of Water Molecule

Shape of water molecule, chemical formula H2O, formed by oxygen and hydrogen existing in solid (ice), liquid, gas form

The molecular formula of the water molecule is H2O. Water molecule is formed by sp3 hybridization. Water molecules contain two bond pairs and two lone pairs.

Due to the presence of lone pairs on the central oxygen atom, the shape of the water molecule is not regular tetrahedral. The H2O molecule is V-shaped with an H-O-H bond angle of 105.5°.

Hydrogen Fluoride Molecule

The molecular formula of hydrogen fluoride is HF. Hydrogen fluoride molecule is formed by sp3-hybridization. The fluorine atom is the central atom in the HF molecule. Hydrogen fluoride molecules contain one bond pair and two lone pairs with linear structures.

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